Watch Chuck Versus the Leftovers

As Chuck and Sarah try to realize a new, safer future, Morgan's past as the Intersect sends them to Vail on one last mission, where they enlist the help of an unlikely source -- the legendary BO DEREK (guest starring as herself -- 10, Fashion House, Tommy Boy). Elsewhere, Jeff and Lester continue their own spy mission. Recurring guest star ANGUS MACFADYEN (Braveheart) appears as Nicholas Quinn.

In the fifth season premiere, without the Intersect in his head or the support of the CIA, the world of espionage is a much more dangerous place for Chuck Bartowski and his team of freelance spies. To start, Carmichael Industries takes on a slick, rich thief named Jean Claude (guest star MARK HAMILL -- Star Wars), and a conniving investor, Roger Bale (guest star CRAIG KILBORN -- The Late Late Show with Craig Kilborn), who has stolen money from some of the world's most dangerous people. Meanwhile, Morgan helps Chuck with a special surprise for Sarah, and, back in the Buy More, Jeff and Lester have taken things to another level with their latest scheme.